Is there an Equilibrium between A scorbic and Dehydroascorbic Acids ?

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Abstract
The previously reported interaction between ascorbate monoanion and dehydroascorbic acid yielding semidehy-droascorbic acid has been shown to be therm odynamically unfeasible and non-existent. No evidence for radical formation in the reinvestigation of the reaction using ESR spectroscopy under careful exclusion of air could be found. Our results show that the detection of the free radical in earlier studies resulted from the reaction of ascorbate with traces of oxygen and/or metals.

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