Highly selective epoxidation of alkenes and styrenes with H2O2 and manganese complexes of the cyclic triamine 1,4,7-trimethyl-1,4,7-triazacyclononane
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 917-918
- https://doi.org/10.1039/cc9960000917
Abstract
In acetone and at subambient temperature, manganese complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane-catalyse the selective oxidation of many alkenes and styrenes to epoxides with an efficient use of H2O2; the regio- and chemo-selectivity resemble those of manganese-porphyrin catalysts.Keywords
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