Vibrational Assignments of Organosilanetriols. II. Crystalline Phenylsilanetriol and Phenylsilanetriol-D3
- 1 September 1978
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 32 (5) , 469-479
- https://doi.org/10.1366/000370278774330874
Abstract
Fourier transform infrared spectra (3800 to 450 cm−1) and laser Raman spectra (4000 to 0 cm−1) of crystalline phenylsilanetriol and phenylsilanetriol-d3, and liquid state phenylsilanetriol and phenylsilanetriol-d3 are first reported. Complete band assignments are attempted. All vibrational modes of the SiOH group except for the SiC torsional mode, including the SiOH in-plane and out-of-plane bending modes, are observed. In addition to the phenylsilanetriols, infrared and laser Raman spectra of crystalline diphenylsilanediol and triphenylsilanol are also studied to aid the band assignments.Keywords
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