Mono(cyclopentadienyl)molybdenum chemistry: hydrido-, halogeno-, allylic, and butadiene derivatives of [1,2-bis(diphenylphosphino)ethane](η-cyclopentadienyl)molybdenum and related compounds
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 1367-1371
- https://doi.org/10.1039/dt9790001367
Abstract
The new compounds [Mo(η-C5H5)2L2][PF6]2, [Mo(η-C5H5)(η3-C5H7)(dppe)], [Mo(η-C5H5)L2Cl3], [Mo(η-C5H5)(dppe)H3], [Mo(η-C5H5)(dppe) Br3]·C6H5Me, [Mo(η-C5H5)2(NCMe)2][PF6]2, [Mo(η-C5H5)2(dppm)H][PF6], [Mo(η-C5H5)(dppm)Cl][PF6]·0.5CH2Cl2, and [Mo(η-C5H5)(exo-H-C5H5)(dppm)][PF6]·CH2Cl2[L2= 1,2-bis (diphenylphosphino)ethane (dppe) or bis(diphenylphosphino)methane (dppm)] have been prepared. The trihydride [Mo(η-C5H5)(dppe)H3] reacts with butadiene giving [Mo(η-C5H5)(dppe)(η3-C3H4Me)].Keywords
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