Quantum corrections to the properties of a dense fluid with non-analytic intermolecular potential function
- 1 July 1975
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 30 (1) , 1-11
- https://doi.org/10.1080/00268977500101711
Abstract
The problem of calculating quantum corrections to the properties of a dense fluid whose molecules interact via pair potentials which are non-analytic functions of the intermolecular separation is studied. Expressions are given for the first and second quantum corrections to the free energy, and the first quantum correction to the radial distribution function. In the latter case it is important to include terms which, although negligible as far as thermodynamic properties are concerned, contribute significantly to the radial distribution function in regions near the potential singularities.Keywords
This publication has 25 references indexed in Scilit:
- Quantum Corrections to the Virial Coefficients for Potentials with Hard CoresPhysical Review A, 1973
- Approximate Evaluation of the Second-Order Term in the Perturbation Theory of FluidsThe Journal of Chemical Physics, 1970
- On the Theory of Quantum Corrections to the Equations of State and to the Particle-Distribution FunctionsJournal of Mathematical Physics, 1970
- Quantum-Mechanical Equation of State of a Hard-Sphere Gas at High Temperature. IIPhysical Review B, 1969
- Quantum Corrections to the Second Virial Coefficient at High TemperaturesJournal of Mathematical Physics, 1968
- Suppression at High Temperature of Effects Due to Statistics in the Second Virial Coefficient of a Real GasPhysical Review B, 1965
- High-Temperature Equation of State by a Perturbation Method. I. Nonpolar GasesThe Journal of Chemical Physics, 1954
- The caloric and thermal equation of state in quantum statistical mechanicsPhysica, 1949
- The quantum theory of the non-ideal gas I. Deviations from the classical theoryPhysica, 1936
- On the Quantum Correction For Thermodynamic EquilibriumPhysical Review B, 1932