Covalency in metal ion–sulphate interaction

Abstract
Frequencies of the 3P1â†�1S0 transition for tin(II), antimony(III), thallium(I), lead(II), and bismuth (III) in sulphate environments are compared with those for the metal ions in aqueous and chloride environments. The trend in the sp separation follows a similar trend for the β values previously obtained from crystal-field data, but contrasts with optical electronegativity data.
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