Phonon self-energy in LiTaO3and LiNbO3

Abstract
Infrared reflection spectra (extraordinary ray) of lithium niobate and lithium tantalate in the temperature range 300-1300 K exhibit a feature which cannot be described correctly with an additional classical oscillator and which is understood as a phonon self-energy effect. Comparison is made with room-temperature Raman data where two additional peaks in the same spectral region have been assigned to a fundamental polar phonon mode activated by a distortion of the structure.