Substituted Methanes. IV. Vibrational Spectra and Calculated Thermodynamic Properties of Deuterotrichloromethane
- 1 August 1950
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 18 (8) , 1081-1083
- https://doi.org/10.1063/1.1747864
Abstract
Raman displacements, semiquantitative relative intensities, quantitative depolarization factors, and wave numbers and percent transmission for the infra‐red bands in the region 400–5000 cm−1 have been obtained for CCl3D. Thermodynamic properties—heat content, free energy, entropy, and heat capacity—have been calculated from the spectroscopic and molecular structure data, to a rigid rotator, harmonic oscillator approximation, for nine temperatures from 298.16° to 1000°K.Keywords
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