Intercalation of Metallocenes in the Layered Transition-Metal Dichalcogenides
- 20 June 1975
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 188 (4194) , 1210-1211
- https://doi.org/10.1126/science.188.4194.1210
Abstract
Novel intercalation complexes of many of the layered transition-metal dichalcogenides incorporating the metallocenes of cobalt and chromium have been prepared. Evidence is presented indicating a configuration in which the five-membered rings of the metallocene guest are situated perpendicular to the slabs of the dichalcogenide host. In the complexes the metallocenes apparently behave as pseudo-alkali metals, transferring an electron to the chalcogenide.Keywords
This publication has 2 references indexed in Scilit:
- Intercalation Complexes of Lewis Bases and Layered Sulfides: A Large Class of New SuperconductorsScience, 1971
- Organometallic CompoundsPublished by Springer Nature ,1968