Functionalizations and bridgehead reactivity of 4-homoisotwistane (tricyclo[5,3,1,03,8]undecane). Synthesis of 3-substituted derivatives
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 371-372
- https://doi.org/10.1039/c39750000371
Abstract
Bromination and hydride transfer-carboxylation of 4-homoisotwistane (tricyclo[5,3,1,03,8]undecane)(I) to give the 3-substituted derivatives (II) and (III) as well as ready hydrolysis of the 3-bromide (II) shows the high reactivity of the 3-bridgehead in the hydrocarbon (I).Keywords
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