Thermodynamic acid dissociation constants of aromatic thiols
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 14,p. 1969-1971
- https://doi.org/10.1039/p29730001969
Abstract
The thermodynamic acid dissociation constants of thiophenol and a series of meta- and para-substituted thiophenols have been measured in water at 25°C by the e.m.f.–spectrophotometric method. The results and the significance of the linear free energy relationship for thiophenols are discussed and compared with the limited data available in the literature.Keywords
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