Propylene carbonate stabilized nanostructured palladium clusters as catalysts in Heck reactions
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1921-1922
- https://doi.org/10.1039/cc9960001921
Abstract
Nanostructured Pd clusters, prepared either electrochemically using a sacrificial Pd anode or by thermolysis of Pd(O2CMe)2, are stable in propylene carbonate even at 140–155 °C; such colloidal solutions catalyse Heck reactions in the absence of phosphine ligands.Keywords
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