A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms: synthesis and X-ray structure of the anion [Rh14N2(CO)25]2?
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 26-27
- https://doi.org/10.1039/c39910000026
Abstract
The novel anion [Rh14N2(CO)25]2–, obtained by pyrolysis of [Rh6N(CO)15]–, contains a metal-centred tetradecanuclear metallic polyhedron, with two interstitial nitrogen atoms, both five-connected to rhodium atoms.Keywords
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