Rotational transitions in molecule–solid scattering
- 1 April 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (7) , 2730-2735
- https://doi.org/10.1063/1.430805
Abstract
A quantum mechanical calculation of the collision of H2 with the (001) face of LiF has been carried out and compared with recent experimental data in which rotational transitions were resolved. A simple model potential accounts quantitatively for many of the observed effects. Refined potential parameters are extracted and the effects of some of these parameters on rotational transitions are discussed.Keywords
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