Alkyl-ligand α-CH interaction with a rhenium–oxygen multiple bond in ReO2R3, R = CH2CMe3or CH2SiMe3
- 1 January 1988
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 313-315
- https://doi.org/10.1039/c39880000313
Abstract
An X-ray crystallographic analysis of ReO2(CH2CMe3)3 and variable temperature 1H n.m.r. studies involving ReO2R3, R = CH2CMe3 or CH2SiMe3, suggest that α-C–H ORe interactions occur in the complexes.Keywords
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