Fluxional processes in organotransition-metal C60 complexes
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 793-794
- https://doi.org/10.1039/a700385d
Abstract
Variable-temperature and EXSY 13 C NMR studies on [M(NO)(PPh 3 ) 2 (η 2 -C 60 )] (M = Co, Rh), [Ru(NO)(PPh 3 ) 2 (η 2 -C 60 )H] and [Rh(CO)(PPh 3 ) 2 (η 2 -C 60 )H] show the presence of C 60 –metal moiety rotation and migration processes and the data allow extensive assignment of δ(C 60 ) 13 C NMR resonances.Keywords
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