Kinetics of curing reaction of epoxide catalyzed by tertiary amine
- 10 November 1993
- journal article
- research article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 50 (6) , 1099-1106
- https://doi.org/10.1002/app.1993.070500618
Abstract
The kinetic study of the curing reaction of epoxide catalyzed by tertiary amine was carried out through thermal analysis of the reaction by differential scanning calorimetry (DSC). Using infrared spectroscopy (IR) and neutron magnetic reasonance (NMR) analysis, a reaction mechanism for this reaction was proposed. The reaction proceeded to anionic polymerization. An autocatalytic reaction was induced at high concentration of the tertiary amine catalyst. © 1993 John Wiley & Sons, Inc.Keywords
This publication has 11 references indexed in Scilit:
- Polymerization of epoxides in the presence of tertiary amino alcoholsJournal of Polymer Science Part A: Polymer Chemistry, 1990
- Acceleration mechanisms in curing reactions involving model systemsMakromolekulare Chemie. Macromolecular Symposia, 1987
- Polymerization of p-cresyl glycidyl ether induced by benzyldimethylamineEuropean Polymer Journal, 1985
- Curing reaction of epoxy resins with diaminesJournal of Applied Polymer Science, 1984
- Nonlinear constrained optimization of filled polyestersJournal of Applied Polymer Science, 1973
- Kinetics and thermal characterization of thermoset curePolymer Engineering & Science, 1973
- Determination of cure of diallyl phthalate using differential scanning calorimetryPolymer Engineering & Science, 1972
- Calorimetric investigation of polymerization reactions. IV. Curing reaction of polyester fumarate with styreneJournal of Polymer Science Part A-1: Polymer Chemistry, 1970
- The mechanism of the crosslinking of epoxide resins by aminesPolymer, 1961
- Reaction Kinetics in Differential Thermal AnalysisAnalytical Chemistry, 1957