Self assembly in custom designed cyclodextrins
- 1 December 1994
- journal article
- research article
- Published by Taylor & Francis in Supramolecular Chemistry
- Vol. 4 (3) , 243-246
- https://doi.org/10.1080/10610279408029476
Abstract
Synthesis of the first custom designed cyclodextrins obtained by a nucleophilic attack on hepatkis-2,3-epoxy-β-cyclodextrin is reported. This novel cyclodextrin provides amine functionalities in addition to hydroxyl groups for chemical processes. Spectral evidence shows that the cavity in this new cyclodextrin is flexible and it self assembles into a dimer under specific conditions.Keywords
This publication has 10 references indexed in Scilit:
- Preparation and Molecular Recognition Ability of Mono[6-deoxy-6-(l-tyrosylamino)]-β-cyclodextrin. Formation and Guest Binding Properties of Distorted Cavity Formed Outside the Parent CyclodextrinBulletin of the Chemical Society of Japan, 1993
- Heptakis-2,3-epoxy-β-cyclodextrin, a key intermediate in the synthesis of custom designed cyclodextrinsJournal of the Chemical Society, Chemical Communications, 1992
- Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐OrganizationAngewandte Chemie International Edition in English, 1990
- Miniature organic models of enzymesAccounts of Chemical Research, 1987
- Artificial EnzymesCold Spring Harbor Symposia on Quantitative Biology, 1987
- Transaminations by pyridoxamine selectively attached at C-3 in .beta.-cyclodextrinJournal of the American Chemical Society, 1983
- Selective sulfonation of a secondary hydroxyl group of β-cyclodextrinTetrahedron Letters, 1982
- Improved acylation rates within cyclodextrin complexes from flexible capping of the cyclodextrin and from adjustment of the substrate geometryJournal of the American Chemical Society, 1980
- Cyclodextrin ChemistryPublished by Springer Nature ,1978
- Acceleration of phenyl ester cleavage by cycloamyloses. A model for enzymic specificityJournal of the American Chemical Society, 1967