Entropy, dynamics, and instantaneous normal modes in a random energy model
- 1 December 2000
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 62 (6) , 7905-7908
- https://doi.org/10.1103/physreve.62.7905
Abstract
It is shown that the fraction of imaginary-frequency instantaneous normal modes (INM) may be defined and calculated in a random energy model (REM) of liquids. The configurational entropy and the averaged hopping rate among the states, R, are also obtained and related to with the results and The proportionality between R and is the basis of existing INM theories of diffusion, so the REM further confirms their validity. A link to opens new avenues for introducing INM into dynamical theories. Liquid states are usually defined by assigning a configuration to the minimum to which it will drain, but the REM naturally treats saddle barriers on the same footing as minima, which may be a better mapping of the continuum of configurations to discrete states. Requirements for a detailed REM description of liquids are discussed.
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This publication has 25 references indexed in Scilit:
- Instantaneous Normal Mode Approach to Liquid State DynamicsThe Journal of Physical Chemistry A, 1997
- The role of localization in glasses and supercooled liquidsThe Journal of Chemical Physics, 1996
- The Instantaneous Normal Modes of LiquidsAccounts of Chemical Research, 1995
- A Topographic View of Supercooled Liquids and Glass FormationScience, 1995
- Instantaneous Normal Modes and the Glass TransitionPhysical Review Letters, 1995
- Normal mode analysis of liquid CS2: Velocity correlation functions and self-diffusion constantsThe Journal of Chemical Physics, 1994
- Instantaneous normal mode analysis of liquid waterThe Journal of Chemical Physics, 1994
- Unstable modes in liquids density of states, potential energy, and heat capacityThe Journal of Chemical Physics, 1993
- Isobaric diffusion constants in simple liquids and normal mode analysisThe Journal of Chemical Physics, 1991
- Normal-mode analysis of liquid-state dynamicsThe Journal of Chemical Physics, 1989