Matrix reactions of magnesium atoms with ozone. Infrared spectra of MgO, MgO2, and MgO3 in solid nitrogen
- 15 July 1978
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 69 (2) , 556-563
- https://doi.org/10.1063/1.436646
Abstract
The magnesium–ozone reaction has been studied by condensing the reagents with nitrogen at 14 K. Isotopic substitution with 26Mg, 16,18O3, and 18O3 has identified infrared absorptions due to two different Mg+O−3 species, MgO2 and MgO. Six isotopic MgO molecules support this infrared detection of MgO which shows a blue matrix shift. Analogous argon matrix reactions produced only Mg+O−3 and two isomeric MgO3 species.Keywords
This publication has 25 references indexed in Scilit:
- Laser photoluminescence spectra of diatomic magnesium (24Mg2 and 26Mg2) in solid argon at 12 KJournal of the American Chemical Society, 1978
- Visible absorption and resonance Raman spectra of alkaline earth metal ozonides in argon and nitrogen matrices at 10 KJournal of Molecular Spectroscopy, 1977
- Matrix isolation of Mg2 and Mgn molecules in neon, argon, and nitrogen hostsJournal of Molecular Spectroscopy, 1976
- Comment on the ir study of the magnesium-discharged oxygen doped argon matrix reactionJournal of Molecular Structure, 1975
- Nitrogen matrix reactions of alkaline earth metal atoms with ozone: Infrared spectra of the alkaline earth metal oxide moleculesThe Journal of Chemical Physics, 1975
- Matrix reactions of alkaline earth metal atoms with oxygen molecules: Infrared spectra of the metal superoxide and metal dioxide speciesThe Journal of Chemical Physics, 1975
- ESR spectrum and structure of NaO3The Journal of Chemical Physics, 1974
- Infrared spectroscopic evidence of the Mg3O3 molecule formed by reaction of magnesium and oxygen atoms in inert gas matrices at 20.4°KJournal of Molecular Structure, 1973
- Argon matrix Raman and infrared spectra and vibrational analysis of ozone and the oxygen-18 substituted ozone moleculesThe Journal of Physical Chemistry, 1972
- Electronic Polarizabilities of Ions in CrystalsPhysical Review B, 1953