The Kirkwood–Salsburg equations for a bounded stable Kac potential. I. General theory and asymptotic solutions
- 1 September 1977
- journal article
- research article
- Published by AIP Publishing in Journal of Mathematical Physics
- Vol. 18 (9) , 1729-1734
- https://doi.org/10.1063/1.523480
Abstract
We derive for Kac potentials of the form γsψ (λx) an expansion, for all the distribution functions, in powers of γs (s=dimension) and prove for z<?cr that the expansion is at least asymptotic. The coefficients in the expansion are shown to be solutions of linear operator equations similar to the Kirkwood–Salsburg equation. We also explicitly obtain a rather simple expression for the coefficients of γs and show that they are given by solving the Ornstein–Zernicke integral equation with the choice of −βψ (y) for the direct correlation function.Keywords
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