Demonstration of a novel method for the controlled deposition of metals onto surfaces by preparation of a Pd–Hg/SiO2catalyst for the selective hydrogenation of alkynes to alkenes
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 997-998
- https://doi.org/10.1039/c39930000997
Abstract
Treatment of silica gel that has SiH functional groups bonded to the surface, with methanolic PdCI2 and then aqueous Hg2S04 affords a new catalytic material for the chemo- and stereo-selective partial hydrogenation of alkynes to Z-alkenes with a high degree of functional group compatibility.Keywords
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