New variational treatment of the ground state of solid helium
- 1 May 1976
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 13 (9) , 3790-3798
- https://doi.org/10.1103/physrevb.13.3790
Abstract
We use a new variational method recently proposed for treating the ground state of quantum crystals to calculate properties of solid . Key improvements over previous variational calculations include avoiding a low-order cluster expansion in determining the density distribution function, and using a quite general and correctly symmetrized single-particle wave function. The variational calculation, which is unrestricted, predicts the correct solidification density within 10%, but the binding energy is about 0.5°K too low possibly because of a superposition approximation. The pressure is in good agreement with experiment. The density distribution function has a Lindemann ratio of 0.24 in accordance with expectations, but the corresponding single-particle wave function is much more spread out. The important implications this result has for the possible existence of Bose-Einstein condensation in solid , and also for the size of the exchange integral in solid , are briefly discussed.
Keywords
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