Interconversion of auI/II/IIIcentres in thioether macrocyclic complexes: the synthesis, structures and redox properties of [Au([18]aneS6)]PF6and [Au2([15]aneS5)2][B(C6F5)4]2
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1097-1098
- https://doi.org/10.1039/c39930001097
Abstract
The interconversion of mononuclear AuI/II/III centres in thioether macrocyclic complexes is related to the stereochemical properties of the parent AuI species; the structure of [Au([18]aneS6)]+ shows a distorted tetrahedral [2 + 2] coordination at AuI, while the AuI complex of [15]aneS5 is binuclear with AuI ions bridging [15]aneS5 ligands in a macrobicyclic structure.Keywords
This publication has 19 references indexed in Scilit:
- Crown thioether chemistryPublished by Springer Nature ,2006
- Bis(1,4,7‐trithiacyclononane)gold Dication: A Paramagnetic, Mononuclear AuII ComplexAngewandte Chemie International Edition in English, 1990
- Bis(1,4,7‐trithiacyclononan)gold‐Dikation: Ein paramagnetischer, einkerniger AuII‐KomplexAngewandte Chemie, 1990
- Chemistry of Thioether Macrocyclic ComplexesAdvances in Inorganic Chemistry, 1990
- [Ag2([15]aneS5)2]2+: a binuclear silver(I) complex incorporating asymmetrically bridging thioether donors. ([15]aneS5= 1,4,7,10,13-pentathiacyclopentadecane)Journal of the Chemical Society, Chemical Communications, 1990
- Silver thioether chemistry: Synthesis, X-ray crystal structure and redox properties of [Ag([18]aneS6)]+ ([18]aneS6 = 1,4,7,10,13,16-hexathiacyclooctadecane)Polyhedron, 1989
- Gold thioether chemistry: synthesis, structure, and redox interconversion of [Au([9]aneS3)2]+/2+/3+([9]aneS3= 1,4,7-trithiacyclononane)Journal of the Chemical Society, Chemical Communications, 1989
- Relativistic effects in structural chemistryChemical Reviews, 1988
- Synthesis and reactivity of perchlorate bis(tetrahydrothiophen)gold(I). 197Au Mössbauer spectra of three-coordinate gold(I) complexesInorganica Chimica Acta, 1986
- Relativistic effects on chemical propertiesAccounts of Chemical Research, 1979