Synthesis of (+)-14-hibanone
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 886-887
- https://doi.org/10.1039/c39720000886
Abstract
Acetolysis of the tetracyclic epimeric alcohols, precursors of the biogenetic intermediate postulated by Edwards, which were prepared from Δ8(14)-podocarpen-13-one via a photochemical adduct with dichloroethylene, leads to (+)-14α-hibyl acetate, ultimately converted into (+)-14α-hibaone.Keywords
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