Nonlinear Dependence of Fish Bioconcentration on n-Octanol/Water Partition Coefficient

Abstract
The log-log relationship between the bioconcentration tendency of organic chemicals in fish and the n−octanol/water partition coefficients breaks down for very hydrophobic compounds. The use of parabolic and bilinear models allows this problem to be overcome. The QSAR equation log BCF = 0.910 log P - 1.975 log (6.8 10−7 P + 1) - 0.786 (n = 154; r = 0.950; s = 0.347; F = 463.51) was found to be a good predictor of bioconcentration in fish.