LIMONOIDS FROM MELIA AZEDARACH LINN. VAR. JAPONICA MAKINO. II. THE NATURAL HYDROXYL PRECURSOR OF SENDANIN

5 January 1978

journal article
research article
Published by Oxford University Press (OUP) in Chemistry Letters

Vol. 7 (1) , 99-102
https://doi.org/10.1246/cl.1978.99

Abstract

Because sendanin is an artifact which has been isolated from M. azedarach Linn. var. japonica Makino only after the acetylation of crude limonoid fraction, the structure of the natural hydroxyl precursor was studied. The chemical and spectroscopic evidence revealed that it was an epimeric mixture of the hemiacetal 5.

Keywords

STRUCTURE
LIMONOID
MELIA AZEDARACH
VAR
LINN
ACETYLATION
ARTIFACT
EPIMERIC

This publication has 1 reference indexed in Scilit:

Constitution and stereochemistry of enmein, a diterpene from isodon trichocarpus kudo
Tetrahedron, 1966