Electron Localization in Dense Ammonia Vapor
- 21 January 1980
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 44 (3) , 211-213
- https://doi.org/10.1103/physrevlett.44.211
Abstract
Electron mobility measurements have been performed in subcritical and supercritical ammonia vapor in the density range from 6× to 3× molecules/ and in the temperature range of 210 to 440 K. In the density range from 2× to about 3× molecules/ an anomalous decrease of electron mobility by more than two powers of ten is observed with increasing vapor density, indicating a "transition" from the delocalized to the localized electron state.
Keywords
This publication has 11 references indexed in Scilit:
- Effects of density and temperature on mobilities of electrons in vapors and liquids of pentane isomers: Molecular structure effectsThe Journal of Chemical Physics, 1979
- Ion mobilities in gaseous ammoniaCanadian Journal of Chemistry, 1978
- Effects of phase density on ionization processes and electron localization in fluidsCanadian Journal of Chemistry, 1977
- Density Dependence of the Absorption Spectrum of solvated Electrons in Supercritical AmmoniaBerichte der Bunsengesellschaft für physikalische Chemie, 1971
- Mobility of Electrons in Low-Temperature Helium GasPhysical Review B, 1967
- Anomalous Electron Mobility and Complex Negative Ion Formation in Low-Temperature Helium VaporPhysical Review Letters, 1962
- Drift Velocities of Slow Electrons in Helium, Neon, Argon, Hydrogen, and NitrogenPhysical Review B, 1961
- Theory of Low-Energy Electron Scattering by Polar MoleculesPhysical Review B, 1957
- THE RESISTANCE-TEMPERATURE COEFFICIENT OF CONCENTRATED SOLUTIONS OF SODIUM IN LIQUID AMMONIAJournal of the American Chemical Society, 1922
- SOLUTIONS OF METALS IN NON-METALLIC SOLVENTS. VI. THE CONDUCTANCE OF THE ALKALI METALS IN LIQUID AMMONIA.3Journal of the American Chemical Society, 1921