Coupling of ethylidyne and carnbonyl ligands leading to a µ3η2bonded propynolate anion induced by one-electron reduction of [Fe3(CO)9(µ3-CO)(µ3CMe)][PPh4]: X-ray crystal structure of [Fe3(CO)9(µ3, µ2-MeCCO)][PPh4]2
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 432-433
- https://doi.org/10.1039/c39840000432
Abstract
The electrochemical one-electron reduction of [Fe3(CO)9(µ3-CO)(µ3CMe)][PPh4] leads to a product containing a µ3,η2 bonded propynolate anion, [Fe3(CO)9(µ3, η2-MeCCO)][PPh4]2.Keywords
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