Chloride ion effects on kinetic resolution in Pd-catalysed allylic alkylation

1 January 1998

journal article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 21,p. 2321-2322
https://doi.org/10.1039/a806324i

Abstract

Chloride ion (5 mol%) accelerates and stabilises the oxidative addition of the slow-reacting enantiomer of cyclopentenyl pivaloate to Pd⁰ complexes bearing the Trost modular ligand.

Keywords

CATALYSED ALLYLIC
CYCLOPENTENYL PIVALOATE
OXIDATIVE ADDITION
ALLYLIC ALKYLATION
COMPLEXES BEARING
PD CATALYSED
TROST MODULAR
REACTING ENANTIOMER
ION EFFECTS
KINETIC RESOLUTION

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