PREPARATION PROCESS AND CATALYTIC ACTIVITY OF CsxH3−xPW12O40

Abstract
When H3PW12O40 solution was titrated with Cs2CO3 solution, Cs2PW12O40 was precipitated at the Cs/anion ratio of 0.5–2, while Cs3HPW12O40 was formed at the ratio of 3. Based on these results, the peculiar variation with x and heat-treatment observed for catalytic activity of CsxH3−xPW12O40 has been explained.

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