Properties of polyamide-based catalysts. Part I. Hydrodehalogenation of chlorobenzene
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 14,p. 1479-1482
- https://doi.org/10.1039/p29750001479
Abstract
The activities and selectivities of platinum–, rhodium–, and palladium–poly-p-phenyleneterephthalamide catalysts were compared for the hydrodehalogenation of chlorobenzene, and differences in reactivity with respect to conventional AI2O3-based catalysts were disclosed. Conversions of PhCI decrease in the order Pd > Rh > Pt. A reaction mechanism is proposed to interpret the results.Keywords
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