Complexes of sulphur bis(t-butylimide) with some transition metals
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 40-43
- https://doi.org/10.1039/dt9750000040
Abstract
The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}](I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2](II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2But)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.Keywords
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