Mass spectrometric identification of cadmium(II) chlorobromide
- 1 January 1972
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 25 (1) , 23-25
- https://doi.org/10.1071/ch9720023
Abstract
Mass spectrometric studies above solid CdCl2 + CdBr2 mixtures in the temperature range 720-770 K have revealed the existence of "mixed halide" gaseous species of formula CdClBr. The heat of formation of CdClBr(g) from CdCl2(g) and CdBr2(g) has been found to be 0.4 � 1 kcal/mol. It is reasoned that the driving force for "mixed halide" formation is associated with a decrease in molecular symmetry.Keywords
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