Tuning of reactivity in epoxidation of alkenes by iron and ruthenium complexes associated to non-porphyrinic ligands

Abstract
RuCl3·n(H2O) or FeSO4 associated with bipyridyl or substituted phenanthrolines, catalyse the expoxidation of stilbenes by IO4 or ClO; using phenanthrolines bearing electron donating or withdrawing groups, it is possible to modulate the reactivity of these systems.

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