Specific hydromagnesiation of prop-2-ynylic alcohols. A simple and specific route to terpenoids
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 718-720
- https://doi.org/10.1039/c39810000718
Abstract
Hydromagnesiation of prop-2-ynylic alcohols proceeds with stereo- and regio-specificity, affording, under mild conditions, the alkenylmagnesium halides (5) in almost quantitative yields, thus providing a novel and simple route to terpenoids.Keywords
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