Crystal structure of β′-Fe0.33V2O5
- 1 May 1994
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Kristallographie - Crystalline Materials
- Vol. 209 (5) , 413-417
- https://doi.org/10.1524/zkri.1994.209.5.413
Abstract
Fe0.33V2O5 crystallizes in the monoclinic space group C2/m with a = 15.307(8) Å, b = 3.624(2) Å, c = 10.123(5) Å, β = 107.30(3)°, V = 536.12 Å3, and Z = 6. The structure was determined from single crystal X-ray diffraction data and it is related to the β-MxV2O5 structure type. There are some indications of partial cationic order between V4+ and V5+ within the three vanadium sites. Fe2+ occupies two crystallographic sites with tetrahedral and 3 + 1 coordination, respectively.Keywords
This publication has 3 references indexed in Scilit:
- Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenidesActa Crystallographica Section A, 1976
- Recherches recentes sur les bronzes de vanadium I. Elements d'insertion monovalentsMaterials Research Bulletin, 1966
- Polarization correction for crystal-monochromatized X-radiationActa Crystallographica, 1955