Lead chromium sulfide, PbCr2S4, and some isotypic compounds

Abstract
The compounds PbCr2S4, SrCr2S4, BaCr2S4, EuCr2S4, SrCr2Se4 and EuCr2Se4 have been prepared and characterized. The compounds are isostructural with a hexagonal structure; the unit‐cell dimensions of PbCr2S4 are: a = 21.411 Å; c = 3.478 Å c/a = 0.1624. PbCr2S4 is a ferrimagnetic semi‐conductor with a Curie temperature of 138°K.

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