Overview Lecture The Lewis acid-base concepts: recent results and prospects for the future
- 1 January 1991
- journal article
- Published by Taylor & Francis in Journal of Adhesion Science and Technology
- Vol. 5 (1) , 1-21
- https://doi.org/10.1163/156856191x00792
Abstract
Since many of the applications of the Lewis acid-base concepts to problems in the field of surface chemistry are dependent on the use of the three basic models of Lewis acid-base phenomena introduced in the 1960s (the HSAB principle, the E & C equation, and the DN-AN approach), this overview lecture briefly summarizes and comments on the published literature on these models that has appeared since they were least reviewed in 1980. It also comments on the problem of extending them to the multi-site interactions characteristic of polymers and surfaces and suggests some possible directions for future work in this area.Keywords
This publication has 56 references indexed in Scilit:
- Molecular hardness and softness, local hardness and softness, hardness and softness kernels, and relations among these quantitiesThe Journal of Chemical Physics, 1988
- E and C parameters from Hammett substituent constants and use of E and C to understand cobalt-carbon bond energiesInorganic Chemistry, 1987
- Requirements and interpretation of linear free energy relationsJournal of the American Chemical Society, 1984
- An E and C modification of the .beta.-.pi. solvation approachJournal of the American Chemical Society, 1982
- Matching between Lewis acids and Lewis bases on the basis of quantitative softness values and their relation with the stability of the complexes—IJournal of Inorganic and Nuclear Chemistry, 1980
- Proton affinity and the frontier orbital concept. Predictions and pitfallsJournal of the American Chemical Society, 1975
- A Double-Scale Equation for Correlating Enthalpies of Lewis Acid-Base InteractionsJournal of the American Chemical Society, 1965
- Hard and Soft Acids and BasesJournal of the American Chemical Society, 1963
- Chemical effects of steric strainsJournal of the Chemical Society, 1956
- Dissociation of the Addition Compound of Trimethylboron with Quinuclidine; Further Evidence for the Steric Configuration of Triethylamine1Journal of the American Chemical Society, 1948