Electron transfer in oxidative addition reactions of d 6-metal complexes
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 634-635
- https://doi.org/10.1039/c39760000634
Abstract
In the reaction of cis-[Mo(CO)2(Me2PCH2CH2-PMe 2)2] with alkyl halides, electron transfer from the metal substrate to the addendum involves the oxidation of Mo0 to MoII with MoI as the identified paramagnetic intermediate.Keywords
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