Evidence that a dioxirane is not responsible for alkene epoxidation in a ketone–Oxone® system
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 849-850
- https://doi.org/10.1039/cc9960000849
Abstract
An18O labelling study shows that a dioxirane intermediate is probably not responsible for alkene epoxidatoin in a ketone-accelerated Oxone® epoxidation system.Keywords
This publication has 15 references indexed in Scilit:
- Catalytic Epoxidation of Alkenes with OxoneThe Journal of Organic Chemistry, 1995
- Ketone-directed peracid epoxidationTetrahedron Letters, 1994
- Dioxiranes. 20. Preparation and properties of some new dioxiranesJournal of the American Chemical Society, 1992
- Chemistry of dioxiranes. 12. DioxiranesChemical Reviews, 1989
- Dioxiranes: a new class of powerful oxidantsAccounts of Chemical Research, 1989
- Buffered potassium peroxymonosulfate-acetone epoxidation of .alpha.,.beta.-unsaturated acidsThe Journal of Organic Chemistry, 1986
- Dioxiranes: synthesis and reactions of methyldioxiranesThe Journal of Organic Chemistry, 1985
- Epoxidation of alkenes by dioxirane intermediates generated in the reaction of potassium caroate with ketonesThe Journal of Organic Chemistry, 1980
- ON THE FORMATION AND REACTIVITY OF DIOXIRANE INTERMEDIATES IN THE REACTION OF PEROXOANIONS WITH ORGANIC SUBSTRATES*Photochemistry and Photobiology, 1979
- An oxygen-18 isotope shift upon carbon-13 NMR spectra and its application to the study of oxygen exchange kineticsJournal of the American Chemical Society, 1979