An open-framework iron phosphate with large voids, exhibiting spin-crossover
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 14,p. 1305-1306
- https://doi.org/10.1039/a903683k
Abstract
A novel iron phosphate, [(C4N3H16)(C4N3H15)]5+-[Fe5F4(H2PO4)(HPO4)3(PO4)3]5–·H2O, consisting of a Fe–O/F–Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.Keywords
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