New conformational effect: predominance of the axial conformation in spiro[5.2]octan-4-ol derivatives
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 147-148
- https://doi.org/10.1039/c39780000147
Abstract
A new conformational effect, the predominance of the axial conformation in 4-methoxy- and 4-acetoxy-derivatives of spiro[5.2]octane, is reported, and its origin is discussed in terms of orbital interaction together with charge transfer and steric repulsion.Keywords
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