The contribution of ring strain to nucleofugality: the first measurement
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 236-237
- https://doi.org/10.1039/c39820000236
Abstract
Comparison of eliminative ring fission in a cyclopropane and elimination in an acyclic analogue allows determination of acceleration of elimination by ring strain; a factor of a least 1011.7 has been found, the largest for any heterolytic reaction.Keywords
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