A new enantiodivergent procedure utilising the chemoselective dieckmann-type cyclisation of chiral mono-thiol diesters
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1775-1776
- https://doi.org/10.1039/cc9960001775
Abstract
The chiral mono-thiol diester, 1 or 2, is converted to the corresponding enantiomeric cyclised products,(–)-7 and (+)-7 or (–)-9, and (+)-9, depending on whether LDA or AlCl3–Et3N is used.Keywords
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