Modeling of coal liquefaction kinetics based on reactions in continuous mixtures. Part II: Comparison with experiments on catalyzed and uncatalyzed liquefaction of coals of different rank
- 1 August 1986
- journal article
- research article
- Published by Wiley in AIChE Journal
- Vol. 32 (8) , 1288-1300
- https://doi.org/10.1002/aic.690320807
Abstract
Experimental kinetic data for three Australian coals are compared with predictions from the mathematical model developed in Part I. For these coals, as well as data reported for North American coals, the model is found to show good agreement, using the characteristic molecular weight as the only parameter. The effects of reaction time and temperature are coupled via a severity index that arises in the model as a dimensionless reaction time. The model is also shown to be applicable when catalysts are present. The product distribution for a particular coal seems to be a function only of the conversion even in the presence of catalysts, as long as the chemical reaction controls the rate of liquefaction.Keywords
This publication has 30 references indexed in Scilit:
- Hydroliquefaction of Victorian brown coal in a continuous reactor: 1. Effects of residence time, temperature and catalysts on conversionFuel, 1984
- Rapid extraction of products from coal hydrogenation reactions using an ultrasonic bathFuel, 1983
- Hydrogenation of brown coal. 3. Roles of hydrogen and hydrogen-donor solvents in systems catalysed by iron and tin compoundsFuel, 1982
- Evidence for direct interaction of hydrogen with brown coal in tin-catalysed reactionsFuel, 1982
- Chemistry of Texas lignite liquefaction in a hydrogen-donor solvent systemFuel, 1982
- Synergistic catalytic effect in the hydrogenation of Victorian brown coalsFuel, 1982
- Reactivity of coal towards hydrogenation—ranking by kinetic measurementsFuel, 1982
- Effects of in-situ mineral matter and a nickel — molybdenum catalyst on hydrogenation of Liddell coalFuel, 1980
- Initial stage (short residence time) coal dissolutionFuel, 1979
- Effects of Coal Minerals on the Hydrogenation, Desulfurization, and Solvent Extraction of CoalIndustrial & Engineering Chemistry Process Design and Development, 1978