Synthesis of tetraalkylthio-substituted phthalocyanines and their complexation with AgIand PdII
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 497-500
- https://doi.org/10.1039/dt9940000497
Abstract
The synthesis of new metal-free and nickel(II) phthalocyanines substituted with four alkylthio groups SR (R = dodecyl or hexadecyl) is described. The new compounds have been characterized by elemental analyses, and IR, 1H NMR and UV/VIS spectroscopy. The thio donors co-ordinate to AgI and PdII to give 2: 1 metal–nickel phthalocyanine species. The changes in the electronic spectra with respect to increasing concentration of PdII or AgI have been investigated.Keywords
This publication has 15 references indexed in Scilit:
- Unsymmetrical phthalocyanines with a single macrocyclic substituentEuropean Journal of Inorganic Chemistry, 1992
- Synthesis, characterization and electrical properties of phthalocyanines substituted with 17-membered trioxadiaza macrocyclesJ. Chem. Soc., Dalton Trans., 1992
- Efficient synthesis of phthalocyanines and related macrocyclic compounds in the presence of organic basesDyes and Pigments, 1992
- Synthesis and characterization of a new copper(II) phthalocyaninate substituted with four 15-membered tetraazamacrocycles and its water-soluble pentanuclear complexesJ. Chem. Soc., Dalton Trans., 1991
- Synthesis and Complexation of 1,2‐Bis[(monoaza[15]crown‐5)‐N‐yl]glyoxime. Crystal Structure of (1,2‐Bis[(monoaza[15]crown‐5)‐N‐yl]glyoximato)palladium(II)Helvetica Chimica Acta, 1990
- Novel Phthalocyanines with Aza Crown Ether MoietiesEuropean Journal of Inorganic Chemistry, 1989
- Bisaxially coordinated macrocyclic transition metal complexesCoordination Chemistry Reviews, 1988
- Synthesis and characterization of metal-free and metal derivatives of a novel soluble crown-ether-containing phthalocyanineJ. Chem. Soc., Dalton Trans., 1988
- Preparation of a novel, soluble copper phthalocyanine with crown ether moietiesJournal of the Chemical Society, Chemical Communications, 1986
- Syntheses and characterization of heteroatom-bridged metal-free phthalocyanine network polymers and model compoundsMacromolecules, 1984