Formation of a µ-η2:η2-disulfide dinuclear copper(II) complex by thermal decomposition of a thiolate complex via C–S bond cleavage
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 623-624
- https://doi.org/10.1039/c39940000623
Abstract
Thermal decomposition of a thiolatocopper(II) complex Cu(SCPh3)(HB(3,5-Pri 2pz)3)1 yields a novel µ-η2 : η2-disulfide dinuclear copper(II) complex {Cu[HB(3,5-Pri 2pz)3]}2(S2)2 whose crystal structure was determined by X-ray crystallography.Keywords
This publication has 15 references indexed in Scilit:
- X-ray structure of thiolatocopper(II) complexes bearing close spectroscopic similarities to blue copper proteinsJournal of the American Chemical Society, 1992
- Synthetic Approach to the Structure and Function of Copper ProteinsAdvances in Inorganic Chemistry, 1992
- Preparation of complexes containing the [Mo3S(S2)3]4+ core and structure of tris(diethyldithiocarbamato)tris(.mu.-disulfido)(.mu.3-thio)-triangulo-trimolybdenum(IV) iodideInorganic Chemistry, 1991
- Tetrahedral copper(II) complexes supported by a hindered pyrazolylborate. Formation of the thiolato complex, which closely mimics the spectroscopic characteristics of blue copper proteinsJournal of the American Chemical Society, 1990
- An oxygen-centered tetranuclear titanium compound Ti4O(S2)4Cl6Journal of the American Chemical Society, 1989
- Synthesis and structures of the vanadium sulfide cluster compounds (iso-PrC5H4)2V2S4 and (C5H5)2V2S2[S2C2(CF3)2]: the influence of .pi.-bonding on the geometry of the .mu.-disulfido ligandJournal of the American Chemical Society, 1983
- An unusual disulfur-bridged nickel dimer with a Ni2S2 planar framework. An example of binuclear coupling promoted by transition metalsInorganic Chemistry, 1983
- Disulfur complexesCoordination Chemistry Reviews, 1982
- Crystal and molecular structure of the tetra-tetrahydrothiophene adduct of Nb2Br4S3: A species containing a single metalmetal bond and a NbμSμ(S2)Nb bridgeInorganica Chimica Acta, 1980
- The Molecular Structure of a Tricyclic Complex, [SFe(CO)3]2Inorganic Chemistry, 1965