Synthesis of the aglycones of the ravidomycin family of antibiotics
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1528-1530
- https://doi.org/10.1039/c39870001528
Abstract
The preparation of the aglycones of the ravidomycin family of antibiotics is described, involving the palladium-catalysed coupling of appropriate stannanes with a common tetracyclic bromide (5), the synthesis of which involved Meerwein coupling of an aniline derivative (13) with 2,5-dichloro-1,4-benzoquinone followed by a directed Diels–Alder reaction.Keywords
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