The structure of the product from reaction of an equimolar mixture of 1- and 2-bromomethylnaphthalenes with enneacarbonyldi-iron. A new π-complex with a trimethylenemethane-type ligand
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 2,p. 85
- https://doi.org/10.1039/c29700000085
Abstract
The product of reaction of an equimolar mixture of 1- and 2-bromomethylnaphthalenes with Fe2(CO)9 is a new π-complex with a trimethylenemethane ligand which constitutes a part of the 2-naphthylmethyl group, the latter being alkylated in the 4-position of its co-ordinated benzene ring by the 1-naphthylmethyl radical, which does not participate in co-ordination with the iron atom.Keywords
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